{"id":25489,"date":"2023-02-21T18:46:41","date_gmt":"2023-02-21T18:46:41","guid":{"rendered":"https:\/\/notes.aayo.blog\/?p=25489"},"modified":"2023-08-01T15:40:27","modified_gmt":"2023-08-01T15:40:27","slug":"ethers","status":"publish","type":"post","link":"https:\/\/notes.aayo.blog\/index.php\/2023\/02\/21\/ethers\/","title":{"rendered":"ETHERS"},"content":{"rendered":"\n<h2 class=\"wp-block-heading\">Introduction<\/h2>\n\n\n\n<p>The name ether is derived from the Latin word \u2018aether\u2019 which means \u2018to ignite\u2019. At room temperature under high-pressure ether are flammable.<\/p>\n\n\n\n<p>The organic compounds in which the divalent oxygen atom (-O-) is bonded to two same or different alkyl or aryl groups are called ethers.<\/p>\n\n\n\n<p>Classification &amp; Nomenclature<\/p>\n\n\n\n<figure class=\"wp-block-image size-full is-resized\"><img fetchpriority=\"high\" decoding=\"async\" src=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/1111.png\" alt=\"\" class=\"wp-image-25809\" width=\"492\" height=\"193\" srcset=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/1111.png 492w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/1111-300x118.png 300w\" sizes=\"(max-width: 492px) 100vw, 492px\" \/><\/figure>\n\n\n\n<p>Examples<\/p>\n\n\n\n<p>Symmetrical ethers: When two alkyl groups or two aryl groups attached with \u2013 O \u2013 are same, such ethers are termed as symmetrical ethers<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img decoding=\"async\" width=\"355\" height=\"209\" src=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/21.png\" alt=\"\" class=\"wp-image-25810\" srcset=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/21.png 355w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/21-300x177.png 300w\" sizes=\"(max-width: 355px) 100vw, 355px\" \/><figcaption class=\"wp-element-caption\">Unsymmetrical ethers: When two alkyl groups or aryl groups attached with \u2013 O \u2013 are different, such ethers are termed unsymmetrical ethers.<br>Isomerism in aliphatic ethers.<br><br><\/figcaption><\/figure>\n\n\n\n<figure class=\"wp-block-image size-full\"><img decoding=\"async\" width=\"654\" height=\"228\" src=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/1-1.png\" alt=\"\" class=\"wp-image-25812\" srcset=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/1-1.png 654w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/1-1-300x105.png 300w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/1-1-600x209.png 600w\" sizes=\"(max-width: 654px) 100vw, 654px\" \/><\/figure>\n\n\n\n<p>Aliphatic ethers can exhibit different types of structural isomerism such as positional isomerism functional isomerism and metamerism, etc. For example Isomers 26 of CHO. Only two isomers are possible among them one is alcohol and the other is ether isomer.<br><\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"270\" height=\"61\" src=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/Capture.png\" alt=\"\" class=\"wp-image-25813\"\/><figcaption class=\"wp-element-caption\"><br>Isomers38 of CHO<br><br>Altogether three isomers are possible, among them two are alcohol isomers and one is ether isomer.<br><\/figcaption><\/figure>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"475\" height=\"86\" src=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/mmmmmm.png\" alt=\"\" class=\"wp-image-25816\" srcset=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/mmmmmm.png 475w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/mmmmmm-300x54.png 300w\" sizes=\"(max-width: 475px) 100vw, 475px\" \/><\/figure>\n\n\n\n<p>Isomers4 of CH10O<\/p>\n\n\n\n<p>Altogether seven isomers are possible among them four are alcohol isomers and three are ether isomers (metamers).<br><\/p>\n\n\n\n<figure class=\"wp-block-image size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/hhhhh.png\" alt=\"\" class=\"wp-image-25819\" width=\"529\" height=\"174\" srcset=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/hhhhh.png 654w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/hhhhh-300x99.png 300w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/hhhhh-600x197.png 600w\" sizes=\"(max-width: 529px) 100vw, 529px\" \/><\/figure>\n\n\n\n<h3 class=\"wp-block-heading\">Method of preparation- Williamson\u2019s Synthesis<\/h3>\n\n\n\n<h4 class=\"wp-block-heading\">Synthesis of Aliphatic ethers:<\/h4>\n\n\n\n<p>When alkyl halide (or haloalkane) heated with sodium or potassium alkoxide then ether is obtained. This method is commonly known as Williamson\u2019s synthesis.<\/p>\n\n\n\n<p>This reaction is a nucleophilic substitution reaction in which alkoxide ion (such as methoxide, ethoxide etc.) acts as a nucleophile &amp; attacks the positively charged carbon atom of haloalkane to give ether.<\/p>\n\n\n\n<p>This method is applied for the synthesis of both symmetrical as well as unsymmetrical ethers.<\/p>\n\n\n\n<p>Example:<br><\/p>\n\n\n\n<figure class=\"wp-block-image size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/aaaa.png\" alt=\"\" class=\"wp-image-25820\" width=\"507\" height=\"146\" srcset=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/aaaa.png 570w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/aaaa-300x86.png 300w\" sizes=\"(max-width: 507px) 100vw, 507px\" \/><\/figure>\n\n\n\n<p><strong><em>NOTE:<\/em><\/strong><br><em>Secondary and tertiary alkyl halides are not used in Williamson\u2019s ether synthesis because they undergo an elimination reaction to form alkene in presence of alkoxide ion since alkoxide ions are not only nucleophile but also acts as a strong base.<\/em><\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"584\" height=\"261\" src=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/1213.png\" alt=\"\" class=\"wp-image-25824\" srcset=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/1213.png 584w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/1213-300x134.png 300w\" sizes=\"(max-width: 584px) 100vw, 584px\" \/><\/figure>\n\n\n\n<p><em>Therefore, for preparation of unsymmetrical ether sodium or potassium salt of secondary or tertiary alcohol and primary alkyl halide is used.<\/em><\/p>\n\n\n\n<p>Synthesis of Aromatic ether:<\/p>\n\n\n\n<p>Aromatic ethers can also be synthesized by using same Williamson\u2019s synthesis. When haloalkane reacts with sodium phenoxide (or sodium phenolate) then alkoxy benzene is formed.<br><\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"419\" height=\"146\" src=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/mmmmmmmmmmmmmmm.png\" alt=\"\" class=\"wp-image-25825\" srcset=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/mmmmmmmmmmmmmmm.png 419w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/mmmmmmmmmmmmmmm-300x105.png 300w\" sizes=\"(max-width: 419px) 100vw, 419px\" \/><\/figure>\n\n\n\n<p><strong><em>NOTE:<\/em><\/strong><\/p>\n\n\n\n<p><em>But we cannot prepare anisole by reacting with <\/em>Iodobenzene and sodium methoxide because the Carbon- Iodine bond in Iodobenzene acquires a <em>partial double bond character by resonance which is difficult to break by methoxide nucleophile.<\/em><\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"358\" height=\"140\" src=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/aksdjsa.png\" alt=\"\" class=\"wp-image-25826\" srcset=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/aksdjsa.png 358w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/aksdjsa-300x117.png 300w\" sizes=\"(max-width: 358px) 100vw, 358px\" \/><\/figure>\n\n\n\n<p>Physical properties of Aliphatic ethers<\/p>\n\n\n\n<p>Solubility:<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"320\" height=\"159\" src=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/bgfdgdfgd.png\" alt=\"\" class=\"wp-image-25827\" srcset=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/bgfdgdfgd.png 320w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/bgfdgdfgd-300x149.png 300w\" sizes=\"(max-width: 320px) 100vw, 320px\" \/><\/figure>\n\n\n\n<p>Lower members of ethers are slightly soluble in water due to their ability to form intermolecular H-bond with water molecules whereas higher members of ethers are insoluble.<br><\/p>\n\n\n\n<h4 class=\"wp-block-heading\">Boling point:<\/h4>\n\n\n\n<p>Ethers have lower boiling point than its isomeric alcohols because ethers cannot form intermolecular H-bond within them or can only interact through weak dipole-dipole interaction (Van der Waal\u2019s interaction) whereas alcohol can form strong intermolecular H- bond with each other.<br><\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"581\" height=\"184\" src=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-1.png\" alt=\"\" class=\"wp-image-25828\" srcset=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-1.png 581w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-1-300x95.png 300w\" sizes=\"(max-width: 581px) 100vw, 581px\" \/><\/figure>\n\n\n\n<p><\/p>\n\n\n\n<h3 class=\"wp-block-heading\">Chemical properties of diethyl ether (Ethoxyethane)<\/h3>\n\n\n\n<h4 class=\"wp-block-heading\">1. Reaction with air<\/h4>\n\n\n\n<p>When diethyl ether reacts with air in presence of sunlight then diethyl peroxide is formed which is thermally unstable and explode violently on heating. It is very dangerous to distill the old sample of ether. Therefore, ethers are stored in dark colored bottle with iron fillings in it to prevent the formation of diethyl peroxide. If diethyl peroxide is formed by chance it is converted into free ether and iron gets oxidized.<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"553\" height=\"198\" src=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-2.png\" alt=\"\" class=\"wp-image-25829\" srcset=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-2.png 553w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-2-300x107.png 300w\" sizes=\"(max-width: 553px) 100vw, 553px\" \/><\/figure>\n\n\n\n<h4 class=\"wp-block-heading\">2. Reaction with cold conc. HCl &amp; cold conc H2SO4<\/h4>\n\n\n\n<p>In this reaction diethyl ether accepts proton donated form HCl therefore diethyl ether acts as<\/p>\n\n\n\n<p>Bronsted-Lowry base and HCl acts as Bronsted-Lowry acid. The cold conc. H2SO4 when reacts with diethyl ether also give similar result.<br><\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"496\" height=\"180\" src=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-3.png\" alt=\"\" class=\"wp-image-25830\" srcset=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-3.png 496w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-3-300x109.png 300w\" sizes=\"(max-width: 496px) 100vw, 496px\" \/><\/figure>\n\n\n\n<h4 class=\"wp-block-heading\">3. Reaction with HI<\/h4>\n\n\n\n<p>When diethyl ether reacts with HI (or HBr) then C-O bond is broken down.<br><\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"503\" height=\"149\" src=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-4.png\" alt=\"\" class=\"wp-image-25831\" srcset=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-4.png 503w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-4-300x89.png 300w\" sizes=\"(max-width: 503px) 100vw, 503px\" \/><\/figure>\n\n\n\n<h4 class=\"wp-block-heading\">4. Reaction with H2SO4<\/h4>\n\n\n\n<ol class=\"wp-block-list\">\n<li>When diethyl ether is warmed with dil. H2SO4, C-O bond is hydrolyzed then ethanol is produced.<\/li>\n<\/ol>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"440\" height=\"84\" src=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-5.png\" alt=\"\" class=\"wp-image-25832\" srcset=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-5.png 440w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-5-300x57.png 300w\" sizes=\"(max-width: 440px) 100vw, 440px\" \/><\/figure>\n\n\n\n<ol class=\"wp-block-list\" start=\"2\">\n<li>When diethyl ether is warmed with conc. H2SO4, C-O bond is broken down &amp; ethanol &amp; ethyl hydrogen sulphate is produced.<\/li>\n<\/ol>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"640\" height=\"103\" src=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-6.png\" alt=\"\" class=\"wp-image-25833\" srcset=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-6.png 640w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-6-300x48.png 300w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-6-600x97.png 600w\" sizes=\"(max-width: 640px) 100vw, 640px\" \/><\/figure>\n\n\n\n<h4 class=\"wp-block-heading\">5. Reaction with Chlorine<\/h4>\n\n\n\n<ol class=\"wp-block-list\">\n<li>When diethyl ether is reacted with limited chlorine in dark condition then \u03b1, \u03b1- dichloro diethyl ether is formed.<\/li>\n<\/ol>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"597\" height=\"92\" src=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-7.png\" alt=\"\" class=\"wp-image-25834\" srcset=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-7.png 597w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-7-300x46.png 300w\" sizes=\"(max-width: 597px) 100vw, 597px\" \/><\/figure>\n\n\n\n<ol class=\"wp-block-list\" start=\"2\">\n<li>When diethyl ether is reacted with excess chlorine in presence of light then perchloro diethyl ether is formed.<\/li>\n<\/ol>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"605\" height=\"83\" src=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-8.png\" alt=\"\" class=\"wp-image-25835\" srcset=\"https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-8.png 605w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-8-300x41.png 300w, https:\/\/notes.aayo.blog\/wp-content\/uploads\/2023\/03\/image-8-600x82.png 600w\" sizes=\"(max-width: 605px) 100vw, 605px\" \/><\/figure>\n\n\n\n<h3 class=\"wp-block-heading\">Important uses of ether<\/h3>\n\n\n\n<ul class=\"wp-block-list\">\n<li>Ethers are used as organic solvents in laboratories and industries.<\/li>\n<\/ul>\n\n\n\n<ul class=\"wp-block-list\">\n<li> Lower ethers are used as general anesthetics.<\/li>\n\n\n\n<li><sup> <\/sup>Ethers are used in various organic reactions like Wurtz reaction, Grignard\u2019s reaction, etc<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"<p>Introduction The name ether is derived from the Latin word \u2018aether\u2019 which means \u2018to ignite\u2019. At room temperature under high-pressure ether are flammable. The organic compounds in which the divalent oxygen atom (-O-) is bonded to two same or different alkyl or aryl groups are called ethers. Classification &amp; Nomenclature Examples Symmetrical ethers: When two [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":26025,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_uag_custom_page_level_css":"","site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"disabled","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"footnotes":""},"categories":[1],"tags":[],"class_list":["post-25489","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-uncategorized"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v23.0 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>Ethers Notes For Grade 12 NEB<\/title>\n<meta name=\"description\" content=\"Here, we have posted notes of Ethers Grade 12 NEB . 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At room temperature under high-pressure ether are flammable. The organic compounds in which the divalent oxygen atom (-O-) is bonded to two same or different alkyl or aryl groups are called ethers. Classification &amp; Nomenclature Examples Symmetrical ethers: When two&hellip;","_links":{"self":[{"href":"https:\/\/notes.aayo.blog\/index.php\/wp-json\/wp\/v2\/posts\/25489"}],"collection":[{"href":"https:\/\/notes.aayo.blog\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/notes.aayo.blog\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/notes.aayo.blog\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/notes.aayo.blog\/index.php\/wp-json\/wp\/v2\/comments?post=25489"}],"version-history":[{"count":3,"href":"https:\/\/notes.aayo.blog\/index.php\/wp-json\/wp\/v2\/posts\/25489\/revisions"}],"predecessor-version":[{"id":26024,"href":"https:\/\/notes.aayo.blog\/index.php\/wp-json\/wp\/v2\/posts\/25489\/revisions\/26024"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/notes.aayo.blog\/index.php\/wp-json\/wp\/v2\/media\/26025"}],"wp:attachment":[{"href":"https:\/\/notes.aayo.blog\/index.php\/wp-json\/wp\/v2\/media?parent=25489"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/notes.aayo.blog\/index.php\/wp-json\/wp\/v2\/categories?post=25489"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/notes.aayo.blog\/index.php\/wp-json\/wp\/v2\/tags?post=25489"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}